A Novel Heme-Thiolate Peroxygenase AaeAPO and Its - download pdf or read online

By Xiaoshi Wang

during this thesis, Xiaoshi Wang investigates the functionality and mechanism of a newly came across heme-thiolate peroxygenase, AaeAPO. This enzyme classification comes from Agrocybe aegerita and is utilized in the conversion of inert hydrocarbons to alcohols. Xiaoshi's paintings makes a speciality of an extracellular P450 enzyme which isn't constrained in its balance and absence of solubility and as a result is proper for common business use. the writer demonstrates that the peroxygenase catalyzes quite a lot of reactions. sometimes the writer even describes very tricky variations in molecules which are hugely inert. Her certain investigations offer a mechanistic framework for the way the peroxygenase catalyzes one of these huge variety of reactions. a tremendous spotlight of this thesis is the identity of key short-lived intermediates within the catalytic cycle of the peroxygenase, utilizing speedy kinetic and spectroscopic equipment, in addition to the elucidation of the thermodynamic houses of those high-energy intermediates. This paintings provides new perception into a tremendous category of enzymes.

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A Novel Heme-Thiolate Peroxygenase AaeAPO and Its Implications for C-H Activation Chemistry (Springer Theses) by Xiaoshi Wang


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